Product ID:03650XX11, UNOCAL GUARDOL 10W
MSDS Date:06/11/1990
FSC:9150
NIIN:00N017614
MSDS Number: BPJNW

UNION OIL COMPANY OF CALIFORNIA

1201 WEST 5TH ST
LOS ANGELES, CA 90017
US

Emergency Phone: 800-356-3129;800-424-9300(CHEMTREC)

Info Phone: 213-977-7589

Cage: 5W523

UNION OIL COMPANY OF CALIFORNIA

7600 SCHAUMBURG, IL 60196 US

Telephone: 800-438-2968

Cage: 5W523

SHOULD BE WORN AS NEEDED.

RTECS: 9999999ZZ

MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY

CAS: 64742-65-0

RTECS: PY8038500

Fraction By Weight: SEE ING

OSHA PEL 5 MG/M3 (OIL MIST)

ACGIH TLV: 5MG/M3;10STEL (MIST)

MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (MILD)

CAS: 64742-54-7

RTECS: PY8035500

Fraction By Weight: SEE ING

OSHA PEL 5 MG/M3 (OIL MIST)

ACGIH TLV: 5 MG/M3;10STEL(MIST)

FRESH AIR. IF SYMP PERSIST, SEEK MED ATTN.

RTECS: 9999999ZZ

DFCLTYS DEVELOP, O*2 SHOULD BE ADMIN BY QUALIFIED

RTECS: 9999999ZZ

NORMALLY REQUIRED. HOWEVER, IF SYMPTOMS DEVELOP,

RTECS: 9999999ZZ

STORM DRAINS, & NATURAL WATERWAYS. DIKE FOR

RTECS: 9999999ZZ

NOTIFY FIRE AUTH & APPROP FED, ST & LOC AGENCIES. IF

RTECS: 9999999ZZ

ZONE, OR ADJOINING SHORELINES, NOTIFY NATIONAL

RTECS: 9999999ZZ

"EMPTY" DRUMS SHOULD BE COMPLETELY DRAINED,

RTECS: 9999999ZZ

RECONDITIONER. ALL OTHER CONTAINERS SHOULD BE

RTECS: 9999999ZZ

MAY BE REQUIRED. WHERE EXPLOSIVE MIXTURES MAY BE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE: MATL MAY CAUSE MILD EYE IRRIT.
DIRECT CONT W/LIQ/EXPOS TO VAPS/MISTS MAY CAUSE STINGING, TEARING &
REDNESS. SKIN: MATL MAY CAUSE MILD SKIN IRRIT. PRLNGD/RPTD
CONT/EXPOS TO VAPS/MISTS MAY CAUSE RE DNESS & BURNING,& DRYING &
CRACKING OF SKIN. NO HARMFUL EFTS ARE EXPECTED FROM SKIN ABSORP OF
MATL. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CAS NOS. 64742-65-0 AND 64742-54-7 ARE
LISTED BY RTECS AS IARC GROUP 1 CARCINOGENS.
Effects of Overexposure:HLTH HAZ: PERSONS W/PRE-EXISTING SKIN DISORDERS
MAY BE MORE SUSCEPTIBLE TO EFTS OF MATL. INHAL: WHILE MATL HAS LOW
DEGREE OF TOX, BRTHG HIGH CONC OF VAPS/MISTS MAY CAUSE IRRIT OF
NOSE & THROAT. INGEST : WHILE MATL HAS LOW DEGREE OF TOX, INGEST OF
EXCESSIVE QTYS MAY CAUSE IRRIT OF DIGEST TRACT. COMMENTS: USED
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE: MOVE VICTIM AWAY FROM EXPOS & INTO FRESH AIR. FLUSH EYES
W/CLEAN H*2O. IF SYMP PERSIST, SEEK MED ATTN. SKIN: WIPE MATL FROM
SKIN & REMOVE CONTAM SHOES & CLTHG. CLEANSE AFFECTED AREA(S) THORO
BY W ASHING W/MILD SOAP & H*2O &, IF NEC, A WATERLESS SKIN
CLEANSER. IF IRRIT/REDNESS DEVELOPS & PERSISTS, SEEK MED ATTN.
INHAL: IF RESP SYMP DEVELOP, MOVE VICTIM AWAY FROM SOURCE OF EXPOS
& INTO (ING 5)

Flash Point Method:COC
Flash Point:401F,205C
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, FOAM OR WATER
SPRAY IS RECOMMENDED.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT
EQUIP.STOP SPILL/RELS IF IT CAN BE DONE W/OUT RISK.MOVE UNDAMAGED
CNTNRS FROM FIRE AREA IF IT CAN BE DONE (SUPDAT)
Unusual Fire/Explosion Hazard:MATL MAY BURN, BUT WILL NOT IGNITE
READILY. IF CNTNR IS NOT PROPERLY COOLED, IT MAY EXPLO IN HEAT OF
FIRE. VAPS ARE HVR/AIR AND MAY ACCUMULATE IN LOW AREAS.

Spill Release Procedures:MAY IGNITE. KEEP SOURCES OF IGNIT AWAY FROM
SPILL/RELS. STAY UPWIND & AWAY FROM SPILL/RELS. ISOLATE AREA &
LIMIT ENTRY TO AUTH PERS. STOP SPILL/RELS IF IT CAN BE DONE W/OUT
RISK. WEAR APPROP PROT EQUI P. PVNT SPILLED MATL FROM ENTERING
SEWERS, (ING 8)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:USE & STORE IN COOL, DRY, WELL
VENTILATED AREAS AWAY FROM HEAT & ALL SOURCES OF IGNITION. KEEP
CONTAINER(S) CLOSED. STORE ONLY IN APPRVD CONTAINERS.
Other Precautions:PROT CNTNR(S) AGAINST PHYS DMG. "EMPTY" CNTNRS RETAIN
RESIDUE & CAN BE DANGEROUS. DO NOT PRESS, CUT,WELD,BRAZE,
SOLDER,DRILL, GRIND OR EXPOS CNTNRS TO HEAT, FLAME, SPARKS/OTHER
SOURCES OF IGNIT; THEY MAY EXPLO & CAUSE INJ/DEATH. (ING 11)

Respiratory Protection:USE OF RESPIRATORY PROT IS ADVISED WHEN CONC
EXCEED ESTABLISHED EXPOS LIMITS. DEPENDING ON AIRBORNE
CONCENTRATION, USE NIOSH/MSHA APPROVED RESPIRATOR OR GAS MASK
W/APPROP CARTRIDGES & CANNISTERS OR NI OSH/MSHA APPRVD SUPPLIED AIR
EQUIPMENT.
Ventilation:IF CURRENT VENT PRACT ARE NOT ADEQ TO MAINTAIN AIRBORNE
CONC BELOW ESTABLISHED EXPOS LIMITS, ADNL VENT/EXHST SYS(ING 13)
Protective Gloves:IMPERMEABLE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:IT IS SUGGESTED THAT SOURCE OF CLEAN H*2O BE
AVAIL IN WORK AREA FOR FLUSHING EYES & SKIN. IMPERVIOUS CLTHG (ING
14)
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT WEAR
CONTAMINATED CLOTHING OR SHOES. USE GOOD PERSONAL HYGIENE PRACTICE.
Supplemental Safety and Health
FIRE FIGHT PROC: W/OUT RISK. H*2O SPRAY MAY BE USEFUL IN MIN/DISPERSING
VAPS & COOLING EQUIP EXPOS TO HEAT & FLAME. AVOID SPREADING BURNING
LIQ W/H*2O USED FOR COOLING PURPOSES. EFTS OF OVEREXP: MOTOR OIL
IS POSS SKIN CANCER HAZ BASED ON TESTS IN LAB ANIMALS & HAS BEEN
IDENTIFIED AS POSS CARCINOGEN BY IARC.

Boiling Pt:B.P. Text:>600F,>316C
Vapor Density:>1
Spec Gravity:0.87
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, BROWN LIQUID, CHARACTERISTIC PETROLEUM ODOR.
Percent Volatiles by Volume:NEGLIG

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS CHLORINE, PERMANGANATES AND
DICHROMATES.
Stability Condition to Avoid:EXTENDED EXPOSURE TO HIGH TEMPERATURES.
Hazardous Decomposition Products:COMBUSTION MAY YIELD MAJOR AMOUNTS OF
OXIDES OF CARBON & MINOR AMOUNTS OF NO*X, PO*X, SO*X, ZNO*X.

Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL,
COUNTY, STATE, AND FEDERAL REGULATIONS.

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